NanoWorld, Author at Blog • by NanoWorld® -… – Page 17 of 87 – Blog • by NanoWorld®

Atomistic insights into highly active reconstructed edges of monolayer 2H-WSe 2 photocatalyst

Today, October 9, 2022, is National #NanotechnologyDay in the US. The theme for this year’s National Nanotechnology Day is nanotechnology’s role in understanding and responding to climate change and improving the health of the Earth and its people.

Climate change has necessitated the framing of government regulations and the development of green strategies for reducing CO2 emissions. Scientists worldwide are engaged in efforts to find sustainable solutions to the problem of CO2 level in the air.*

Ascertaining the function of in-plane intrinsic defects and edge atoms is necessary for developing efficient low-dimensional photocatalysts.*

In their article “Atomistic insights into highly active reconstructed edges of monolayer 2H-WSe 2 photocatalyst” Mohammad Qorbani , Amr Sabbah, Ying-Ren Lai, Septia Kholimatussadiah, Shaham Quadir , Chih-Yang Huang, Indrajit Shown, Yi-Fan Huang, Michitoshi Hayashi, Kuei-Hsien Chen and Li-Chyong Chen report the wireless photocatalytic CO2 reduction to CH4 over reconstructed edge atoms of monolayer 2H-WSe2 artificial leaves.*

Their first-principles calculations demonstrate that reconstructed and imperfect edge configurations enable CO2 binding to form linear and bent molecules. Experimental results show that the solar-to-fuel quantum efficiency is a reciprocal function of the flake size. It also indicates that the consumed electron rate per edge atom is two orders of magnitude larger than the in-plane intrinsic defects. Further, nanoscale redox mapping at the monolayer WSe2–liquid interface confirms that the edge is the most preferred region for charge transfer.*

The author’s results pave the way for designing a new class of monolayer transition metal dichal-cogenides with reconstructed edges as a non-precious co-catalyst for wired or wireless hydrogen evolution or CO2 reduction reactions.*

The thickness of the WSe 2 flake was measured by using Atomic Force Microscopy with a NanoWorld Pointprobe® NCHR AFM probe and was controlled by a feedback mechanism. The AFM cantilever was driven under a resonant frequency of ~330 kHz and 42 N m−1 spring constant.*

Figure 4 from “Atomistic insights into highly active reconstructed edges of monolayer 2H-WSe2 photocatalyst” by Mohammad Qorbani et al:
Nanoscale redox mapping and PC performance
a FE-SEM image of the ML WSe2 in dark (control experiment) in the solution containing Ag ions. b FE-SEM images of the ML WSe2 under light after Ag photodeposition for 1 h, respectively. Bright regions show the presence of Ag nanoparticles. Inset illustrates the photoreduction mechanism. Scale bar = 2 μm. c–e AFM height profile measured in the liquid environment, background normalized SECM feedbacks maps for main, and lift scans, respectively. Scale bar = 1 μm. f Color map of the blank-corrected total methane yield as a function of flake sizes (in perimeters) and areas. g Blank-corrected IQE as a function of the average flake perimeter. The black line shows the fitted reciprocal curve. h Stability test for six cycles. Irradiation time for each cycle is 4 h.

*Mohammad Qorbani , Amr Sabbah, Ying-Ren Lai, Septia Kholimatussadiah, Shaham Quadir , Chih-Yang Huang, Indrajit Shown, Yi-Fan Huang, Michitoshi Hayashi, Kuei-Hsien Chen and Li-Chyong Chen
Atomistic insights into highly active reconstructed edges of monolayer 2H-WSe 2 photocatalyst
Nature communications (2022) 13:1256
DOI: https://doi.org/10.1038/s41467-022-28926-0

Please follow this external link to read the full article: https://rdcu.be/cXbA6

Open Access
The article “Atomistic insights into highly active reconstructed edges of monolayer 2H-WSe 2 photocatalyst” by Mohammad Qorbani , Amr Sabbah, Ying-Ren Lai, Septia Kholimatussadiah, Shaham Quadir , Chih-Yang Huang, Indrajit Shown, Yi-Fan Huang, Michitoshi Hayashi, Kuei-Hsien Chen and Li-Chyong Chen is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.

Impact of annealing on electric and elastic properties of 10-nm Hf0.5Zr0.5O2 films prepared on Si by sputtering

HfO2-based films are important materials used in broad range of electronic applications from high-performance transistors and memory cells, to thermoelectric and energy harvesting elements. *

In the article “Impact of annealing on electric and elastic properties of 10-nm Hf0.5Zr0.5O2 films prepared on Si by sputtering” Leonid Bolotov, Shinji Migita, Ryouta Fujio, Manabu Ishimaru, Shogo Hatayama and Noriyuki Uchida described how they used scanning probe methods to make nanoscale comparison of chemical composition, surface morphology, the elastic modulus and the surface potential of bare 10-nm thick Hf0.5Zr0.5O2 films prepared on Si by a carbon-free sputtering process. *

NanoWorld conductive platinum iridium5 coated Pointprobe® EFM AFM probes were used for the electrostatic force microscopy (EFM). *

The composition mapping confirmed uniform distribution of Hf and Zr in the film along wafer size. Suppression of the monoclinic phase in films annealed at 600 – 800 °C had strong impact on spatial variations of film properties. Small surface roughness, large electric domain sizes (50–200 nm at 700 °C) and small fluctuations of the surface potential (40–50 meV) in Si coated with the films are appealing for gate-stack applications. Films annealed at 600-700 °C showed the elastic modulus of about 169 GPa and the ferroelectric polarization reversal at a field of ~1 MV/cm as observed by nanoscale poling with a Pt-coated scanning probe. In contrast, properties of films annealing at 800 °C were affected by growth of thick interfacial oxide layer. *

The nanoscale approach presented in the article is beneficial in optimizing of physical and mechanical properties of thin dielectric films. *

Fig. 3 from Leonid Bolotov et al. “Impact of annealing on electric and elastic properties of 10-nm Hf0.5Zr0.5O2 films prepared on Si by sputtering”: AFM topographs (a, c) and CPD maps (b, d) of 10 nm Hf0.5Zr0.5O2 films on Si: as-grown film (a, b), and annealed at 700 °C (c, d). Rectangular shapes in (c, d) outline one domain. Scale bars are 200 nm. NanoWorld conductive platinum iridium5 coated Pointprobe® EFM AFM probes were used for the electrostatic force microscopy (EFM). — Fig. 3 from Leonid Bolotov et al. “Impact of annealing on electric and elastic properties of 10-nm Hf0.5Zr0.5O2 films prepared on Si by sputtering”:
AFM topographs (a, c) and CPD maps (b, d) of 10 nm Hf0.5Zr0.5O2 films on Si: as-grown film (a, b), and annealed at 700 °C (c, d). Rectangular shapes in (c, d) outline one domain. Scale bars are 200 nm.

*Leonid Bolotov, Shinji Migita, Ryouta Fujio, Manabu Ishimaru, Shogo Hatayama and Noriyuki Uchida
Impact of annealing on electric and elastic properties of 10-nm Hf0.5Zr0.5O2 films prepared on Si by sputtering
Microelectronic Engineering, Volume 258, 1 April 2022, 111770
DOI: https://doi.org/10.1016/j.mee.2022.111770

Open Access The article “Impact of annealing on electric and elastic properties of 10-nm Hf0.5Zr0.5O2 films prepared on Si by sputtering” by Leonid Bolotov, Shinji Migita, Ryouta Fujio, Manabu Ishimaru, Shogo Hatayama and Noriyuki Uchida is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.

Nanoscale Noncollinear Spin Textures in Thin Films of a D2d Heusler Compound

Magnetic nano-objects, namely antiskyrmions and Bloch skyrmions, have been found to coexist in single-crystalline lamellae formed from bulk crystals of inverse tetragonal Heusler compounds with D2d symmetry. *

Skyrmions can be observed in real-space by various direct imaging techniques. *

In the article “Nanoscale Noncollinear Spin Textures in Thin Films of a D2d Heusler Compound” Ankit K. Sharma, Jagannath Jena, Kumari Gaurav Rana, Anastasios Markou, Holger L. Meyerheim, Katayoon Mohseni, Abhay K. Srivastava, Ilya Kostanoskiy, Claudia Felser and Stuart S. P. Parkin describe the use of magnetic force microscopy (MFM) imaging to investigate magnetic textures in epitaxial thin films of [001]-oriented Mn2RhSn formed by magnetron sputtering.*

They find evidence for magnetic nano-objects which exhibit a wide range of sizes with stability with respect to magnetic field and temperature that is similar to single-crystalline lamellae. *

However, the nano-objects do not form well-defined arrays, nor is any evidence found for helical spin textures. This is speculated to likely be a consequence of the poorer homogeneity of chemical ordering in the thin films. *

Evidence is found for elliptically distorted nano-objects along perpendicular crystallographic directions within the epitaxial films, which is consistent with elliptical Bloch skyrmions observed in single-crystalline lamellae. Thus, these measurements provide strong evidence for the formation of noncollinear spin textures in thin films of Mn2RhSn. *

Using these films, it is shown that individual nano-objects can be deleted using a local magnetic field from a magnetic AFM tip and collections of nano-objects can be similarly written. *

For writing and deleting the nano-objects, magnetic AFM probes from NanoWorld of the Pointprobe® MFMR type were used. *

These observations described in the article suggest a path toward the use of these nano-objects in thin films with D2d symmetry as magnetic memory elements paving the way to the realization of skyrmionic devices based on Heusler thin films. *

Figure 5 from Ankit K. Sharma et al. Nanoscale Noncollinear Spin Textures in Thin Films of a D2d Heusler Compound : Controlled creation and annihilation of nano-objects in a 35 nm-thick Mn2RhSn thin film. a) Schematic illustration of magnetization orientations of MFM tip and sample for writing. The distance between tip and the sample is the scan height z. b–e) MFM images in zero field and z = 80, 40, 30, and 20 nm, respectively at 200 K. f) Contact-mode image in zero field and 200 K. The blue and red colors represent up and down magnetization, respectively. Images in (b)–(f) are at the same scale: a scale bar is given in (f). g–i) MFM images taken at z = 70, 50, and 30 nm at 100 K under Hz = 180 mT. Images in (g)–(i) are at the same scale: a scale bar is given in (i). For writing and deleting the nano-objects, magnetic AFM probes from NanoWorld of the Pointprobe® MFMR type were used. — Figure 5 from Ankit K. Sharma et al. Nanoscale Noncollinear Spin Textures in Thin Films of a D2d Heusler Compound :
Controlled creation and annihilation of nano-objects in a 35 nm-thick Mn2RhSn thin film. a) Schematic illustration of magnetization orientations of MFM tip and sample for writing. The distance between tip and the sample is the scan height z. b–e) MFM images in zero field and z = 80, 40, 30, and 20 nm, respectively at 200 K. f) Contact-mode image in zero field and 200 K. The blue and red colors represent up and down magnetization, respectively. Images in (b)–(f) are at the same scale: a scale bar is given in (f). g–i) MFM images taken at z = 70, 50, and 30 nm at 100 K under Hz = 180 mT. Images in (g)–(i) are at the same scale: a scale bar is given in (i).

*Ankit K. Sharma, Jagannath Jena, Kumari Gaurav Rana, Anastasios Markou, Holger L. Meyerheim, Katayoon Mohseni, Abhay K. Srivastava, Ilya Kostanoskiy, Claudia Felser, Stuart S. P. Parkin
Nanoscale Noncollinear Spin Textures in Thin Films of a D2d Heusler Compound
Advanced Materials, Volume 33, Issue 32, August 12, 2021, 2101323
DOI: https://doi.org/10.1002/adma.202101323

Open Access The article “Nanoscale Noncollinear Spin Textures in Thin Films of a D2d Heusler Compound” Ankit K. Sharma, Jagannath Jena, Kumari Gaurav Rana, Anastasios Markou, Holger L. Meyerheim, Katayoon Mohseni, Abhay K. Srivastava, Ilya Kostanoskiy, Claudia Felser and Stuart S. P. Parkin is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.